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Glucovanillin

Also written vanillin glucoside, vanillin β-D-glucoside

PhenolicC14H18O8Aroma

Quick answer

Vanillin bound to a sugar: the form in which a green vanilla pod holds its flavour, odourless until curing frees the vanillin.

What it does

Mature green vanilla beans are flavourless; the characteristic flavour forms only through curing. In one batch of Hainan beans glucovanillin made up 10.67 per cent of the dry weight of the fresh bean, against 0.03 per cent free vanillin, and through curing it fell to 0.17 per cent while vanillin rose to between 2.7 and 3.0 per cent.

Strong evidenceSources: Metabolite Transformation and Enzyme Activi… (Introduction; Sections 2.3 and 2.4)

How it behaves when cooked

Four properties of the molecule, and what they mean at the stove.

Volatility
low
Fat solubility
low
Water solubility
high
Heat stability
moderate

The whole of vanilla curing is the release of vanillin from glucovanillin, and the chemistry is less simple than the usual account. In the batch studied, most of the vanillin appeared during the six days of sweating, yet the β-glucosidase that splits glucovanillin lost all measurable activity through blanching and sweating; activity reappeared during drying, reaching a quarter of the fresh bean’s, and the authors link it to microorganisms that appear on the bean after sweating. The vanillin found was much smaller than the glucovanillin lost, and the authors note that drying and curing can themselves lose vanillin. A cook meets only the result: a cured pod with little glucovanillin left in it.

Strong evidenceSources: Metabolite Transformation and Enzyme Activi… (Sections 2.3–2.5)

Spices that carry it

Recorded on the compound rather than on each spice, so the two cannot disagree.

  • VanillaPrincipal component

    The precursor of vanillin in the green pod. A small amount survives curing — 0.17 per cent of dry weight in the cured beans of the one study read.

Not to be confused with

Compounds a reader is likely to take for this one, and why they differ.

  • Vanillin

    Glucovanillin is vanillin joined to glucose. Vanillin is the aroma; glucovanillin is the odourless store from which curing releases it.

Questions this page answers

  • why do green vanilla pods not smell of vanilla
  • what is glucovanillin